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  On the origin of π-facial diastereoselectivity in nucleophilic additions to chiral carbonyl compounds. 1. Rotational profiles of propionaldehyde 1, chloroacetaldehyde 2, and 2-chloropropionaldehyde 3

Frenking, G., Köhler, K. F., & Reetz, M. T. (1991). On the origin of π-facial diastereoselectivity in nucleophilic additions to chiral carbonyl compounds. 1. Rotational profiles of propionaldehyde 1, chloroacetaldehyde 2, and 2-chloropropionaldehyde 3. Tetrahedron, 47(43), 8991-9004. doi:10.1016/S0040-4020(01)86504-2.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-7CD7-5 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-7CD8-4
Genre: Journal Article

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 Creators:
Frenking, G.1, Author
Köhler, K. F.1, Author
Reetz, M. T.1, Author           
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: The conformational profiles for rotation around the C-C(=O) bond α and the energy minimum conformations are calculated for propionaldehyde 1, chloroacetaldehyde 2, and 2-chloropropionaldehyde 3 at MP2/6-31G(d)//HF/6-31G(d). The energy level of the LUMO is calculated as a function of α for 1, 2, and 3 and discussed in relationship to the Felkin-Anh model.

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Language(s): eng - English
 Dates: 1991-06-121991-11-04
 Publication Status: Issued
 Pages: 14
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0040-4020(01)86504-2
 Degree: -

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Title: Tetrahedron
  Abbreviation : Tetrahedron
Source Genre: Journal
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Publ. Info: Kidlington : Elsevier Science
Pages: - Volume / Issue: 47 (43) Sequence Number: - Start / End Page: 8991 - 9004 Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/00404020