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  Stereoselective Synthesis of γ-Aminocarboxylates

Reetz, M. T., & Röhrig, D. (1989). Stereoselective Synthesis of γ-Aminocarboxylates. Angewandte Chemie, International Edition in English, 28(12), 1706-1709. doi:10.1002/anie.198917061.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-7CBB-5 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-A379-2
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Röhrig, Dirk1, Author
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1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: 1,3-Allyl strain may explain the high diastereoselectivity observed in the conversion of optically active α-amino acids 1 into the homochiral γ-amino acid esters 3. The esters 2, accessible via the α-N,N dibenzylaminoaldehydes, are intermediates in this synthesis, and subsequent cuprate addition leads stereoselectively to the products 3.

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Language(s): eng - English
 Dates: 1989-07-121989-12-01
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.198917061
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Title: Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem., Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 28 (12) Sequence Number: - Start / End Page: 1706 - 1709 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833