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  Stereoselective Addition of Lithiated Heterocycles to Chiral α-Amino Aldehydes

Reetz, M. T., Reif, W., & Holdgrün, X. (1989). Stereoselective Addition of Lithiated Heterocycles to Chiral α-Amino Aldehydes. Heterocycles, 28(2), 707-710.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-8141-6 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-8142-5
Genre: Journal Article

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 Creators:
Reetz, M. T.1, Author           
Reif, W.1, Author
Holdgrün, X.1, Author
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: Lithiated heterocycles LiR (R = 2-furyl, 2-thienyl, 2-pyridyl, etc.) add diastereoselectively to optically active α-N,N-dibenzylamino aldehydes (PhCH2)2NCHR1CHO (R1 = PhCH2, Me, Me2CH, Me3CSiMe2OCH2, etc.) with 80-95% nonchelation control to give syn alcs. (PhCH2)2NCHR1CHROH (same R, R1).

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Language(s): eng - English
 Dates: 1989-10-01
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: -
 Degree: -

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Title: Heterocycles
Source Genre: Journal
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Publ. Info: Sendai, Japan : Elsevier
Pages: - Volume / Issue: 28 (2) Sequence Number: - Start / End Page: 707 - 710 Identifier: ISSN: 0385-5414
CoNE: https://pure.mpg.de/cone/journals/resource/954925528872