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  Asymmetric C-C bond formation using organometallic chemistry

Reetz, M. T. (1988). Asymmetric C-C bond formation using organometallic chemistry. Pure and Applied Chemistry, 60(11), 1607-1614. doi:10.1351/pac198860111607.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-7D12-2 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-7D13-1
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
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1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: Boron enolates having C2-symmetric ligands (cf. 11) add to aldehydes high enantioselectrively, as do chirally modified allylboron reagents 21. Diastereofacial selective Grignard and aldol additions to α-aminoaldehydes 28 are possible with chelation or non-chelation control, depending upon the type of protective group and nature of the organometallic reagent. Using the proper organometallic reagents, electrophilic or nucleophilic additions to chiral olefins occur diastereoselectively.

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Language(s): eng - English
 Dates: 1988
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1351/pac198860111607
 Degree: -

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Title: Pure and Applied Chemistry
  Abbreviation : Pure Appl. Chem.
Source Genre: Journal
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Publ. Info: Oxford : International Union of Pure and Applied Chemistry.
Pages: - Volume / Issue: 60 (11) Sequence Number: - Start / End Page: 1607 - 1614 Identifier: ISSN: 0033-4545
CoNE: https://pure.mpg.de/cone/journals/resource/954925436486