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  α-Alkylation of carbonyl compounds using 1-acetoxy-1-ferrocenylethane

Reetz, M. T., & Sauerwlad, M. (1987). α-Alkylation of carbonyl compounds using 1-acetoxy-1-ferrocenylethane. Journal of Organometallic Chemistry, 328(1-2), 155-160. doi:10.1016/S0022-328X(00)99775-4.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-7D20-2 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-7D21-1
Genre: Journal Article

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 Creators:
Reetz, M. T.1, Author           
Sauerwlad, M.1, Author
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: 1-Acetoxy-1-ferrocenylethane reacts with ZnX2 to form the corresponding secondary carbocation, which adds to the double bond to enoxysilanes derived from ketones, carboxylic acid esters, or lactones. This C-C bond-forming reaction provides an extremely mild and efficient way of alkylating carbonyl compounds at the α-position to form novel ferrocene derivatives.

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Language(s): eng - English
 Dates: 1986-12-171987-07-14
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0022-328X(00)99775-4
 Degree: -

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Title: Journal of Organometallic Chemistry
  Abbreviation : J. Organomet. Chem.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 328 (1-2) Sequence Number: - Start / End Page: 155 - 160 Identifier: ISSN: 0022-328X
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228