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  The First Direct Evidence for a Cram Chelate

Reetz, M. T., Hüllmann, M., & Seitz, T. (1987). The First Direct Evidence for a Cram Chelate. Angewandte Chemie, International Edition in English, 26(5), 477-479. doi:10.1002/anie.198704771.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-7D4C-2 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-A36A-3
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Hüllmann, Michael1, Author
Seitz, Thomas1, Author
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: 30 years after their postulation, the existence of Cram chelates has now been demonstrated 13C-NMR spectroscopically with the examples 2a/2b. They are formed from 1 and CH3TiCl3. As shown by labeling experiments and kinetic measurements the methyl transfer 2 → 3 proceeds intermolecularly (not intramolecularly).

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Language(s): eng - English
 Dates: 1987-01-091987-05-01
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.198704771
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Title: Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem., Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 26 (5) Sequence Number: - Start / End Page: 477 - 479 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833