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  Selective reactions of organotitanium reagents

Reetz, M. T. (1985). Selective reactions of organotitanium reagents. Pure and Applied Chemistry, 57(12), 1781-1788. doi:10.1351/pac198557121781.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-7FD3-6 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-7FD4-5
Genre: Journal Article

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 Creators:
Reetz, M. T.1, Author           
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: Classical"carbanions" can be titanated to form reagents whichbehave chemo—, regio— and stereoselectively in reactions with alkylhalides and carbonyl compounds. The nature of the ligands at Ti(IV) determines the electronic and steric properties of the reagents. This is usefulin predicting the stereochemical outcome in reactions with alkoxy carbonylcompounds. TiCl4 can also be used for stereoselective C—C bond formation.

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Language(s): eng - English
 Dates: 1985-12-01
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1351/pac198557121781
 Degree: -

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Title: Pure and Applied Chemistry
  Abbreviation : Pure Appl. Chem.
Source Genre: Journal
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Publ. Info: Oxford : International Union of Pure and Applied Chemistry.
Pages: - Volume / Issue: 57 (12) Sequence Number: - Start / End Page: 1781 - 1788 Identifier: ISSN: 0033-4545
CoNE: https://pure.mpg.de/cone/journals/resource/954925436486