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  Trimethylsilyl cyanide promoted cyanation of tertiary alkyl chlorides and other SN1 active compounds

Reetz, M. T., Chatziiosifidis, I., Künzer, H., & Müller-Starke, H. (1983). Trimethylsilyl cyanide promoted cyanation of tertiary alkyl chlorides and other SN1 active compounds. Tetrahedron, 39(6), 961-965. doi:10.1016/S0040-4020(01)88594-X.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-8307-6 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-8308-5
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Chatziiosifidis, Ioannis1, Author
Künzer, Hermann1, Author
Müller-Starke, Hans1, Author
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: Tertiary chlorides are readily cyanated in a one-pot procedure using trimethylsilyl cyanide in the presence of SnCl4. The mechanism of this novel and synthetically useful reaction involves initial isonitrile formation followed by rearrangement to the tertiary nitrile. Other SN1 active componds also undergo smooth cyanation.

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Language(s): eng - English
 Dates: 1982-04-141983
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0040-4020(01)88594-X
 Degree: -

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Title: Tetrahedron
  Abbreviation : Tetrahedron
Source Genre: Journal
 Creator(s):
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Publ. Info: Kidlington : Elsevier Science
Pages: - Volume / Issue: 39 (6) Sequence Number: - Start / End Page: 961 - 965 Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/00404020