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  Organotitanium reagents in organic synthesis. A simple means to adjust reactivity and selectivity of carbanions

Reetz, M. T. (1982). Organotitanium reagents in organic synthesis. A simple means to adjust reactivity and selectivity of carbanions. In F. L. Boschke (Ed.), Topics in Current Chemistry Vol. 106: Synthesis and Structural Problems (pp. 1-54). Berlin: Springer-Verlag.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-A37B-0 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-B0AA-B
Genre: Book Chapter

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 Creators:
Reetz, Manfred T.1, Author           
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: Classical organometallic reagents such as alkyl-lithium and magnesium compounds as well as a large number of lithiated species which are substituted by resonance-stabilizing groups or hetero-atoms can be convened into the titanium analogs using cheap quenching reagents. This increases
chemoselectivity dramatically and also has a profound influence on stereoseleetivity in reactions with carbonyl compounds. Since the nature of the ligands at titanium can ge varied systematically, it is possible to control the electronic and steric environment at the metal in a predictable manner. Besides increasing selectivity, several novel reaction types are possible.

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Language(s): eng - English
 Dates: 1982
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1007/3-540-11766-0_1
 Degree: -

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Title: Topics in Current Chemistry Vol. 106: Synthesis and Structural Problems
Source Genre: Series
 Creator(s):
Boschke, Friedrich L.1, Editor
Affiliations:
1 Springer-Verlag, Postfach 105280, D-6900 Heidelberg 1, ou_persistent22            
Publ. Info: Berlin : Springer-Verlag
Pages: - Volume / Issue: 106 Sequence Number: - Start / End Page: 1 - 54 Identifier: ISBN: 978-3-540-11766-7