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  Cyanation of Tertiary Alkyl Chlorides: A Novel Method for the Geminal Dialkylation of Ketones

Reetz, M. T., & Chatziiosifidis, I. (1981). Cyanation of Tertiary Alkyl Chlorides: A Novel Method for the Geminal Dialkylation of Ketones. Angewandte Chemie, International Edition in English, 20(12), 1017-1018. doi:10.1002/anie.198110172.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-A3D1-D Version Permalink: https://hdl.handle.net/21.11116/0000-000E-A3D2-C
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Chatziiosifidis, Ioannis1, Author
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1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: The SnCl4-catalyzed CC-Coupling of tertiary alkyl halides (1) with trimethyl-silyl cyanide (2) is of preparative interest; the resulting nitriles (3) can be modified in a number of ways, e.g. by Grignard reaction or reduction. Since the educts (1) are accessible from ketones, the geminal dialkylation of ketones is thus possible.

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Language(s): eng - English
 Dates: 1981-01-121981-12-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.198110172
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Title: Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem., Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 20 (12) Sequence Number: - Start / End Page: 1017 - 1018 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833