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  Chemoselective and Position Specific Methylation of tert-Alkyl Halides with Methyltitanium(IV) Chlorides

Reetz, M. T., Westermann, J., & Steinbach, R. (1980). Chemoselective and Position Specific Methylation of tert-Alkyl Halides with Methyltitanium(IV) Chlorides. Angewandte Chemie, International Edition in English, 19(11), 901-902. doi:10.1002/anie.198009011.

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 Creators:
Reetz, Manfred T.1, Author           
Westermann, Jürgen1, Author
Steinbach, Rainer1, Author
Affiliations:
1Institut für Organische Chemie und Biochemie der Universität, Gerhard-Domagk-Strasse 1, D-5300 Bonn (Germany), ou_persistent22              

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 Abstract: Methylation with methyltitanium reagents promises to have a wide range of application, not least because of its chemoselectivity. In the tert-alkyl chlorides studied, which additonally contained a primary-or sec-alkyl chloride unit or an olefinic double bond, only the tert-C-atom was methylated under favorable conditions.

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Language(s): eng - English
 Dates: 1980-04-241980-11-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.198009011
 Degree: -

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Title: Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem., Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 19 (11) Sequence Number: - Start / End Page: 901 - 902 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833