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  Chemo- and Diastereoselective Addition of Alkyl- and Aryltitanium(IV) Compounds to Aldehydes and Ketones

Reetz, M. T., Steinbach, R., Westermann, J., & Peter, R. (1980). Chemo- and Diastereoselective Addition of Alkyl- and Aryltitanium(IV) Compounds to Aldehydes and Ketones. Angewandte Chemie, International Edition in English, 19(12), 1011-1012. doi:10.1002/anie.198010111.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-A5B8-8 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-A5B9-7
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Steinbach, Rainer1, Author
Westermann, Jürgen1, Author
Peter, Roland1, Author
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: CC bond formation with organotitanium compounds has many advantages. Thus aldehydes react considerably faster than ketones: for instance, PhTi(O-iPr)3 gives > 90% of (1), and 4-tert-butylcyclohexanone forms a 18:82 mixture of equatorial and axial alcohol (2) with Me2TiCl2.

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Language(s): eng - English
 Dates: 1980-10-271980-12-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.198010111
 Degree: -

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Title: Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem., Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 19 (12) Sequence Number: - Start / End Page: 1011 - 1012 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833