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  Adamantene in the Gas Phase

Schwarz, H., Reetz, M. T., Maier, W. F., Wesdemiotis, C., Chatziiosifidis, I., & Schilling, M. (1979). Adamantene in the Gas Phase. Angewandte Chemie, International Edition in English, 18(12), 952-953. doi:10.1002/anie.197909521.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-A7EA-E Version Permalink: https://hdl.handle.net/21.11116/0000-000E-A7ED-B
Genre: Journal Article

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 Creators:
Schwarz, Helmut1, Author
Reetz, Manfred T.2, Author           
Maier, Wilhelm F.2, Author
Wesdemiotis, Chrysostomos1, Author
Chatziiosifidis, Ioannis2, Author
Schilling, Marita1, Author
Affiliations:
1Institut für Organische Chemie der Technischen Universität, Strasse der 17. Juni 135, D-1000 Berlin 12 (Germany), ou_persistent22              
2Institut für Organische Chemie und Biochemie der Universität, Gerhard-Domagk-Strasse 1, D-5300 Bonn (Germany), ou_persistent22              

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 Abstract: Adamentene (2), the “anti-Bredt compound” par excellence, has formerly only been detected by trapping experiments. It has now been generated as the neutral molecule in the mass spectrometer by unimolecular fragmentation of the radical cation (1), R=H or D, at ca. 10−6 torr. This observation was confirmed by comparison with the decomposition of the tert-butyl and cyclohexyl analogs of (1) and by peak shape analyses.

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Language(s): eng - English
 Dates: 1979-05-311979-12-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.197909521
 Degree: -

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Title: Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem., Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 18 (12) Sequence Number: - Start / End Page: 952 - 953 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833