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  Thermal Rearrangement of Silylmethyl Acetates

Reetz, M. T., & Greif, N. (1977). Thermal Rearrangement of Silylmethyl Acetates. Angewandte Chemie, International Edition in English, 16(10), 712-713. doi:10.1002/anie.197707121.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-A893-E Version Permalink: https://hdl.handle.net/21.11116/0000-000E-A894-D
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Greif, Norbert1, Author
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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 Abstract: The inverted ylide (2) is postulated as an intermediate of the intramolecular rearrangement of silylmethyl acctates (1), R3=CH3 or CF3. A concerted dyotropic or a two-step radical process are ruled out, and an ionic mechanism is unlikely.

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Language(s): eng - English
 Dates: 1977-08-041977-10-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.197707121
 Degree: -

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Title: Angewandte Chemie, International Edition in English
  Abbreviation : Angew. Chem., Int. Ed. Engl.
Source Genre: Journal
 Creator(s):
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 16 (10) Sequence Number: - Start / End Page: 712 - 713 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833