ausblenden:
Schlagwörter:
Hyperconjugation; Anitaromaticity
Zusammenfassung:
The electronic structure and heats of formation of several acyloxy cations and the isomeric dioxacyclopropyl cations have been determined by MINDO/2 calculations. The potential energy surface shows the cyclic isomer to represent the least energy species. The stabilizing effect of alkyl substituents in the latter has been traced to strong hyperconjugative interaction.
