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  The electronic structure and energy of acyloxy and dioxacyclopropyl cations

Reetz, M. T., & Maier, W. F. (1974). The electronic structure and energy of acyloxy and dioxacyclopropyl cations. Theoretica Chimica Acta, 35, 163-167. doi:10.1007/BF00551404.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-A95D-C Version Permalink: https://hdl.handle.net/21.11116/0000-000E-A95E-B
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Maier, Wilhelm F.1, Author
Affiliations:
1Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, ou_persistent22              

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Free keywords: Hyperconjugation; Anitaromaticity
 Abstract: The electronic structure and heats of formation of several acyloxy cations and the isomeric dioxacyclopropyl cations have been determined by MINDO/2 calculations. The potential energy surface shows the cyclic isomer to represent the least energy species. The stabilizing effect of alkyl substituents in the latter has been traced to strong hyperconjugative interaction.

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Language(s): eng - English
 Dates: 1974-04-051974-10-01
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1007/BF00551404
 Degree: -

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Title: Theoretica Chimica Acta
  Other : TCHAAM
  Abbreviation : Theor. Chim. Acta
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Heidelberg : Springer-Verlag
Pages: - Volume / Issue: 35 Sequence Number: - Start / End Page: 163 - 167 Identifier: ISSN: 0040-5744
CoNE: https://pure.mpg.de/cone/journals/resource/0040-5744