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Free keywords:
Chemical reactions, Interatomic & molecular potentials, Rotational states
MPINP:
Quantendynamik - Abteilung Blaum
MPINP:
Expt. CSR - Abteilung Blaum
Abstract:
We present a merged-beams study of reactions between HD+ ions, stored in the Cryogenic Storage Ring (CSR), and laser-produced ground-term C atoms. The molecular ions are stored for up to 20 s in the extreme vacuum of the CSR, where they have time to relax radiatively until they reach their vibrational ground state (within 0.5 s of storage) and rotational states with J≤3 (after 5 s). We combine our experimental studies with quasiclassical trajectory calculations based on two reactive potential energy surfaces. In contrast to previous studies with internally excited H2+ and D2+ ions, our results reveal a pronounced isotope effect, favoring the production of CH+ over CD+ across all collision energies, and a significant increase in the absolute rate coefficient of the reaction. Our experimental results agree well with our theoretical calculations for vibrationally relaxed HD+ ions in their lowest rotational states.
