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  Highly photostable and fluorescent microporous solids prepared via solid-state entrapment of boron dipyrromethene dyes in a nascent metal–organic framework

Glembockyte, V., Frenette, M., Mottillo, C., Durantini, A. M., Gostick, J., Štrukil, V., et al. (2018). Highly photostable and fluorescent microporous solids prepared via solid-state entrapment of boron dipyrromethene dyes in a nascent metal–organic framework. Journal of the American Chemical Society, 140(49), 16882-16887. doi:10.1021/jacs.8b09608.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000F-F7EF-E Version Permalink: https://hdl.handle.net/21.11116/0000-000F-F7F0-B
Genre: Journal Article

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 Creators:
Glembockyte, Viktorija1, Author           
Frenette, Mathieu, Author
Mottillo, Cristina, Author
Durantini, Andrés M., Author
Gostick, Jeff, Author
Štrukil, Vjekoslav, Author
Friščić, Tomislav, Author
Cosa, Gonzalo, Author
Affiliations:
1Chemical Biology, Max Planck Institute for Medical Research, Max Planck Society, ou_2364732              

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 Abstract: We report a strategy to synthesize highly emissive, photostable, microporous materials by solid-state entrapment of boron dipyrromethene (BODIPY) fluorophores in a metal–organic framework. Solvent-free mechanochemistry or accelerated aging enabled quantitative capture and dispersal of the PM605 dye within the ZIF-8 framework starting from inexpensive, commercial materials. While the design of emissive BODIPY solids is normally challenged by quenching in a densely packed environment, herein reported PM605@ZIF-8 materials show excellent emissive properties and to the best of our knowledge an unprecedented ∼10-fold enhancement of BODIPY photostability. Time-resolved and steady-state fluorescence studies of PM605@ZIF-8 show that interchromophore interactions are minimal at low dye loadings, but at higher ones lead to through-pore energy transfer between chromophores and to aggregate species.

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Language(s): eng - English
 Dates: 2018-09-052018-11-212018-12-12
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.8b09608
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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 140 (49) Sequence Number: - Start / End Page: 16882 - 16887 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870