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  Arene Ring Expansion by Ruthenium η6-Arene Complexes

Whitehurst, W. G., Schulte, T., Wang, Z., Waldbach, F., & Ritter, T. (2025). Arene Ring Expansion by Ruthenium η6-Arene Complexes. Angewandte Chemie International Edition, 64(6): e202421608. doi:10.1002/anie.202421608.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0010-4340-A Version Permalink: https://hdl.handle.net/21.11116/0000-0010-C144-7
Genre: Journal Article

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 Creators:
Whitehurst, William G.1, Author           
Schulte, Tim1, 2, Author           
Wang, Zikuan3, Author           
Waldbach, Felix1, Author           
Ritter, Tobias1, Author           
Affiliations:
1Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040308              
2Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany, ou_persistent22              
3Research Group Manganas, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541709              

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Free keywords: dearomatization; ruthenium; π-arene
 Abstract: Transition metal π-arene complexes enable the dearomatization of benzene rings to access diversified unsaturated carbocycles through multistep synthetic procedures involving sequential addition of nucleophiles and electrophiles. This work details a single-step dearomatization process by reaction of Ru(η6-arene) complexes with enolates derived from α-halo or α-(tosyloxy)esters to directly transform π-coordinated arenes to ring-expanded cycloheptatrienes.

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Language(s): eng - English
 Dates: 2024-11-062024-11-192025-02-03
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.202421608
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 64 (6) Sequence Number: e202421608 Start / End Page: - Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851