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  Characterization of a Delta(8)-sphingolipid desaturase from higher plants: A stereochemical and mechanistic study on the origin of E,Z isomers

Beckmann, C., Rattke, J., Oldham, N. J., Sperling, P., Heinz, E., & Boland, W. (2002). Characterization of a Delta(8)-sphingolipid desaturase from higher plants: A stereochemical and mechanistic study on the origin of E,Z isomers. Angewandte Chemie, International Edition in English, 41(13), 2298-2300. doi:10.1002/1521-3773(20020703)41:13<2298:AID-ANIE2298>3.0.CO;2-G.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-9E99-8 Version Permalink: https://hdl.handle.net/21.11116/0000-0005-E3EF-E
Genre: Journal Article

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BOL075.pdf (Publisher version), 0B
 
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 Creators:
Beckmann, C.1, Author           
Rattke, J.2, Author           
Oldham, N. J.2, Author           
Sperling, P., Author
Heinz, E., Author
Boland, W.1, Author           
Affiliations:
1Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society, ou_24028              
2Research Group Mass Spectrometry, MPI for Chemical Ecology, Max Planck Society, ou_421899              

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Free keywords: Littoralis sex-pheromone; delta(9) desaturase; (z;e)-9;11- tetradecadienoic acid; (e)-11-tetradecenoic acid; diiron proteins; fatty-acids; biosynthesis; cryptoregiochemistry; stereospecificity; oxidation
 Abstract: The simultaneous formation of E and Z double bonds results from the syn elimination of H and/or D atoms from different conformations of 4‐hydroxysphinganine [D4]1. Δ8‐Sphingolipid desaturase from Helianthus annuus is heterologously expressed in yeast and catalyzes the transformation to E olefin 2 (88%) and Z olefin 3 (12%).

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 Dates: 2002
 Publication Status: Issued
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 Identifiers: Other: BOL075
DOI: 10.1002/1521-3773(20020703)41:13<2298::AID-ANIE2298>3.0.CO;2-G
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Title: Angewandte Chemie, International Edition in English
  Other : Angew. Chem. Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 41 (13) Sequence Number: - Start / End Page: 2298 - 2300 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833