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  Biosynthesis of psoralen: Mechanism of a cytochrome p450 catalyzed oxidative bond cleavage

Stanjek, V., Miksch, M., Lueer, P., Matern, U., & Boland, W. (1999). Biosynthesis of psoralen: Mechanism of a cytochrome p450 catalyzed oxidative bond cleavage. Angewandte Chemie, International Edition in English, 38(3), 400-402. doi:10.1002/(SICI)1521-3773(19990201)38:3<400:AID-ANIE400>3.0.CO;2-K.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-A3AA-D Version Permalink: https://hdl.handle.net/21.11116/0000-0006-724B-6
Genre: Journal Article

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BOL021.pdf (Publisher version), 0B
 
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 Creators:
Stanjek, V., Author
Miksch, M., Author
Lueer, P., Author
Matern, U., Author
Boland, W.1, Author           
Affiliations:
1Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society, ou_24028              

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Free keywords: Biosynthesis Cytochrome Eliminations Furocoumarins Porphyrinoids. Cultured parsley cells Furanocoumarin biosynthesis Hydroxylation Iron. Chemistry & Analysis in Current Contents(R)/Life Sciences. Chemistry in Current Contents(R)/Physical, Chemical & Earth Sciences.
 Abstract: In contrast to the stepwise oxidative dealkylation of steroids [Eq. (1)], (+)‐marmesin (1) is directly converted by the psoralen synthase (a cytochrome P450) into the phototoxic furanocoumarin psoralen (2) and acetone. The dealkylation proceeds as a syn elimination.

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 Dates: 1999
 Publication Status: Issued
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 Rev. Type: -
 Identifiers: Other: BOL021
DOI: 10.1002/(SICI)1521-3773(19990201)38:3<400::AID-ANIE400>3.0.CO;2-K
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Title: Angewandte Chemie, International Edition in English
  Other : Angew. Chem. Int. Ed. Engl.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 38 (3) Sequence Number: - Start / End Page: 400 - 402 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833