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  Incorporation of chirally deuterated putrescines into pyrrolizidine alkaloids: A reinvestigation

Graser, G., Witte, L., Robins, D. J., & Hartmann, T. (1998). Incorporation of chirally deuterated putrescines into pyrrolizidine alkaloids: A reinvestigation. Phytochemistry, 47(6), 1017-1024. doi:10.1016/S0031-9422(98)80064-2.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-A634-E Version Permalink: https://hdl.handle.net/21.11116/0000-0009-3981-5
Genre: Journal Article

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GER026.pdf (Publisher version), 0B
 
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Graser, G.1, Author           
Witte, L., Author
Robins, D. J., Author
Hartmann, T., Author
Affiliations:
1Department of Biochemistry, MPI for Chemical Ecology, Max Planck Society, ou_421893              

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Free keywords: Senecio vulgaris; Asteraceae; root cultures; pyrrolizidine alkaloids; biosynthesis; retronecine; homospermidine; deuterated putrescines H-2 nmr-spectroscopy; homospermidine synthase; biosynthesis; retronecine; spermidine; stereochemistry; chromatography; retrorsine; polyamines
 Abstract: Based on previous tracer work and recent enzymatic studies it can be predicted that incorporation of (S)-1-H-2]putrescine via the symmetrical intermediate homospermidine into the necine base moiety of pyrrolizidine alkaloids (PAs) should proceed with 50

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 Dates: 1998
 Publication Status: Issued
 Pages: -
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 Rev. Type: -
 Identifiers: Other: GER026
DOI: 10.1016/S0031-9422(98)80064-2
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Title: Phytochemistry
  Other : Phytochem
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 47 (6) Sequence Number: - Start / End Page: 1017 - 1024 Identifier: ISSN: 0031-9422
CoNE: https://pure.mpg.de/cone/journals/resource/954925433416