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キーワード:
Secondary orbital interactions
Density-functional theory
Ab-initio
Stepwise mechanisms
Multiresponse data
High-pressure
Basis sets
Molecules
Cycloaddition
Cyclopentadiene.
Chemistry & Analysis in Current Contents(R)/Life Sciences.
Organic Chemistry/Polymer Science in Current Contents(R)/Physical,
Chemical & Earth Sciences.
要旨:
The stereoselectivity of the reaction of furan (1) with maleic anhydride (2) and maleimide (3) was studied experimentally and theoretically. Although the two reactions are highly similar with regard to their preference for endo and exo steroisomers, not
