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  Stereochemistry of the enzymatic reduction of 2-(4-Methoxybenzyl)-1-cyclohaxanone by means of Solanum aviculare cells in vitro

Vanek, T., Wimmer, Z., Macek, T., Saman, D., Svatoš, A., & Romanuk, M. (1989). Stereochemistry of the enzymatic reduction of 2-(4-Methoxybenzyl)-1-cyclohaxanone by means of Solanum aviculare cells in vitro. Biocatalysis, 2(4), 265-272. doi:10.3109/10242428908992036.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-B433-0 Version Permalink: https://hdl.handle.net/21.11116/0000-0009-3B44-9
Genre: Journal Article

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EXT025.pdf (Publisher version), 3MB
 
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Vanek, T., Author
Wimmer, Z., Author
Macek, T., Author
Saman, D., Author
Svatoš, Aleš1, Author           
Romanuk, M., Author
Affiliations:
1External Organization, ou_persistent22              

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 Abstract: During the investigation of chemical properties of the dicyclic system of insect juvenile hormone analogues, biotransformation of 2-(4-methoxybenzyl)-1-cyclohexanone (1) by plant cell cultures was studied. Among other components, the cis-(1S, 2S)- and cis-(1R, 2R)-2-(4-methoxybenzyl)-1-cyclohexanol enantiomers 2a and 2b were found in the reaction mixture. Higher stereoselectivity of the biotransformation was observed for trans-(1S, 2R)-enantiomer 3a formation, which occurred in at least 60% of calculated enantiomeric excess.

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 Dates: 1989
 Publication Status: Issued
 Pages: -
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 Rev. Type: -
 Identifiers: Other: EXT025
DOI: 10.3109/10242428908992036
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Title: Biocatalysis
Source Genre: Journal
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Publ. Info: de Gruyter
Pages: - Volume / Issue: 2 (4) Sequence Number: - Start / End Page: 265 - 272 Identifier: ISSN: 2353-1746
CoNE: https://pure.mpg.de/cone/journals/resource/2353-1746