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  Stabilization of a diamagnetic (ScBr)-Br-I molecule in a sandwich-like structure

Neculai, A. M., Neculai, D., Roesky, H. W., Magull, J., Baldus, M., Andronesi, O., et al. (2002). Stabilization of a diamagnetic (ScBr)-Br-I molecule in a sandwich-like structure. Organometallics, 21(13), 2590-2592. Retrieved from http://pubs.acs.org/doi/pdfplus/10.1021/om020090b.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0012-F392-6 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-E544-8
Genre: Journal Article

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16486.pdf (Publisher version), 0B
 
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Neculai, A. M., Author
Neculai, D., Author
Roesky, H. W., Author
Magull, J., Author
Baldus, M.1, Author              
Andronesi, O.1, Author              
Jansen, M., Author
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1Research Group of Solid State NMR Spectroscopy, MPI for biophysical chemistry, Max Planck Society

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 Abstract: Reaction of a new beta-diketiminato derivative of scandium, LScBr2 (L = Et2NCH2CH2NC(Me)CHC-(Me)NCH2CH2NEt2), with (C3H5)MgBr gave the unexpected scandium complex (LMgBr)(2)ScBr (1), whose structure was established by X-ray analysis, liquid and solid-state NMR, EPR, UV-vis, and magnetic measurements. Correlation of all results leads to the conclusion that the formal oxidation state of scandium in this complex is one (Sc(I)) having no unpaired electrons.

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Language(s): eng - English
 Dates: 2002-06-24
 Publication Status: Published in print
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 Rev. Method: Peer
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Title: Organometallics
Source Genre: Journal
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Pages: - Volume / Issue: 21 (13) Sequence Number: - Start / End Page: 2590 - 2592 Identifier: -