Stabilization of a diamagnetic (ScBr)-Br-I molecule in a sandwich-like structure

Neculai, A. M.; Neculai, D.; Roesky, H. W.; Magull, J.; Baldus, M.; Andronesi, O.; Jansen, M.

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Stabilization of a diamagnetic (ScBr)-Br-I molecule in a sandwich-like structure

Neculai, A. M., Neculai, D., Roesky, H. W., Magull, J., Baldus, M., Andronesi, O., et al. (2002). Stabilization of a diamagnetic (ScBr)-Br-I molecule in a sandwich-like structure. Organometallics, 21(13), 2590-2592. Retrieved from http://pubs.acs.org/doi/pdfplus/10.1021/om020090b.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-F392-6 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-E544-8

Genre: Journal Article

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Neculai, A. M., Author
Neculai, D., Author
Roesky, H. W., Author
Magull, J., Author
Baldus, M.¹, Author
Andronesi, O.¹, Author
Jansen, M., Author

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1Research Group of Solid State NMR Spectroscopy, MPI for biophysical chemistry, Max Planck Society

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Abstract: Reaction of a new beta-diketiminato derivative of scandium, LScBr2 (L = Et2NCH2CH2NC(Me)CHC-(Me)NCH2CH2NEt2), with (C3H5)MgBr gave the unexpected scandium complex (LMgBr)(2)ScBr (1), whose structure was established by X-ray analysis, liquid and solid-state NMR, EPR, UV-vis, and magnetic measurements. Correlation of all results leads to the conclusion that the formal oxidation state of scandium in this complex is one (Sc(I)) having no unpaired electrons.

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Language(s): eng - English

Dates: Date issued: 2002-06-24

Publication Status: Issued

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Rev. Type: Peer

Identifiers: eDoc: 16486
URI: http://pubs.acs.org/doi/pdfplus/10.1021/om020090b

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Title: Organometallics

Source Genre: Journal

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Pages: - Volume / Issue: 21 (13) Sequence Number: - Start / End Page: 2590 - 2592 Identifier: -