English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Stabilization of a diamagnetic (ScBr)-Br-I molecule in a sandwich-like structure

Neculai, A. M., Neculai, D., Roesky, H. W., Magull, J., Baldus, M., Andronesi, O., et al. (2002). Stabilization of a diamagnetic (ScBr)-Br-I molecule in a sandwich-like structure. Organometallics, 21(13), 2590-2592. Retrieved from http://pubs.acs.org/doi/pdfplus/10.1021/om020090b.

Item is

Files

show Files
hide Files
:
16486.pdf (Publisher version), 0B
 
File Permalink:
-
Name:
16486.pdf
Description:
-
OA-Status:
Visibility:
Restricted (UNKNOWN id 303; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Neculai, A. M., Author
Neculai, D., Author
Roesky, H. W., Author
Magull, J., Author
Baldus, M.1, Author           
Andronesi, O.1, Author           
Jansen, M., Author
Affiliations:
1Research Group of Solid State NMR Spectroscopy, MPI for biophysical chemistry, Max Planck Society

Content

show
hide
Free keywords: -
 Abstract: Reaction of a new beta-diketiminato derivative of scandium, LScBr2 (L = Et2NCH2CH2NC(Me)CHC-(Me)NCH2CH2NEt2), with (C3H5)MgBr gave the unexpected scandium complex (LMgBr)(2)ScBr (1), whose structure was established by X-ray analysis, liquid and solid-state NMR, EPR, UV-vis, and magnetic measurements. Correlation of all results leads to the conclusion that the formal oxidation state of scandium in this complex is one (Sc(I)) having no unpaired electrons.

Details

show
hide
Language(s): eng - English
 Dates: 2002-06-24
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 16486
URI: http://pubs.acs.org/doi/pdfplus/10.1021/om020090b
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Organometallics
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 21 (13) Sequence Number: - Start / End Page: 2590 - 2592 Identifier: -