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  Scanning force and scanning near-field optical microscopy of organized monolayers incorporating a nonamphiphilic metal dyad

Kirsch, A. K., Schaper, A., Huesmann, H., Rampi, M. A., Moebius, D., & Jovin, T. M. (1998). Scanning force and scanning near-field optical microscopy of organized monolayers incorporating a nonamphiphilic metal dyad. Langmuir, 14, 3895-3900.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0012-FD29-4 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-E5DB-3
Genre: Journal Article

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 Creators:
Kirsch, A. K.1, Author              
Schaper, A.1, Author              
Huesmann, H., Author
Rampi, M. A., Author
Moebius, D.2, Author              
Jovin, T. M.3, Author
Affiliations:
1Department of Molecular Biology, MPI for biophysical chemistry, Max Planck Society, ou_578628              
2Research Group of Molecular Organized Systems, MPI for biophysical chemistry, Max Planck Society, ou_578548              
3Max Planck Society, ou_persistent13              

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 Abstract: A water-soluble metal complex dyad, Rh(III)-X-Ru(II), was incorporated in monolayers at the air/water interface by cospreading with a positively (eicosylamine) or negatively (stearic acid) charged amphiphile. After transfer of the monolayer onto a mica substrate via the Langmuir-Blodgett technique, a domain structure similar to that at the air/water interface was observed by scanning probe microscopy (SPM). With scanning force microscopy (SFM) we found domains with diameters in the µm range protruding several Å from the interstitial areas. The same structure was imaged with scanning near-field optical microscopy (SNOM) with joint registration of topographic features and ruthenium fluorescence. We present a model for the complex structure of the molecular film compatible with the different microscopy results.

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Language(s): eng - English
 Dates: 2005-07-061998
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 226985
Other: 633
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Title: Langmuir
Source Genre: Journal
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Pages: - Volume / Issue: 14 Sequence Number: - Start / End Page: 3895 - 3900 Identifier: -