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  Scanning force and scanning near-field optical microscopy of organized monolayers incorporating a nonamphiphilic metal dyad

Kirsch, A. K., Schaper, A., Huesmann, H., Rampi, M. A., Moebius, D., & Jovin, T. M. (1998). Scanning force and scanning near-field optical microscopy of organized monolayers incorporating a nonamphiphilic metal dyad. Langmuir, 14, 3895-3900.

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Datensatz-Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-FD29-4 Versions-Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-E5DB-3
Genre: Zeitschriftenartikel

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 Urheber:
Kirsch, A. K.1, Autor           
Schaper, A.1, Autor           
Huesmann, H., Autor
Rampi, M. A., Autor
Moebius, D.2, Autor           
Jovin, T. M.3, Autor
Affiliations:
1Department of Molecular Biology, MPI for biophysical chemistry, Max Planck Society, ou_578628              
2Research Group of Molecular Organized Systems, MPI for biophysical chemistry, Max Planck Society, ou_578548              
3Max Planck Society, ou_persistent13              

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 Zusammenfassung: A water-soluble metal complex dyad, Rh(III)-X-Ru(II), was incorporated in monolayers at the air/water interface by cospreading with a positively (eicosylamine) or negatively (stearic acid) charged amphiphile. After transfer of the monolayer onto a mica substrate via the Langmuir-Blodgett technique, a domain structure similar to that at the air/water interface was observed by scanning probe microscopy (SPM). With scanning force microscopy (SFM) we found domains with diameters in the µm range protruding several Å from the interstitial areas. The same structure was imaged with scanning near-field optical microscopy (SNOM) with joint registration of topographic features and ruthenium fluorescence. We present a model for the complex structure of the molecular film compatible with the different microscopy results.

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Sprache(n): eng - English
 Datum: 2005-07-061998
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: eDoc: 226985
Anderer: 633
 Art des Abschluß: -

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Titel: Langmuir
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 14 Artikelnummer: - Start- / Endseite: 3895 - 3900 Identifikator: -