English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. Item Summary / 
  2. View item

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  Infrared Spectroscopy and Binding Geometries of Oxygen Atoms Bound to Cationic Tantalum Clusters

Fielicke, A., Gruene, P., Haertelt, M., Harding, D., & Meijer, G. (2010). Infrared Spectroscopy and Binding Geometries of Oxygen Atoms Bound to Cationic Tantalum Clusters. Journal of Physical Chemistry A, 114(36), 9755-9761. doi:10.1021/jp102084n.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0010-F59D-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0009-925C-B
Genre: Journal Article

Files

show Files
hide Files
:
TaO_Authorversion.pdf (Preprint), 4MB
 
File Permalink:
-
Name:
TaO_Authorversion.pdf
Description:
-
OA-Status:
Visibility:
Private
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
735592 CTA.pdf (Copyright transfer agreement), 147KB
 
File Permalink:
-
Name:
735592 CTA.pdf
Description:
-
OA-Status:
Visibility:
Private
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
735592.pdf (Correspondence), 79KB
 
File Permalink:
-
Name:
735592.pdf
Description:
-
OA-Status:
Visibility:
Private
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Fielicke, André1, Author           
Gruene, Philipp1, Author           
Haertelt, Marko1, Author           
Harding, Daniel1, Author           
Meijer, Gerard1, Author           
Affiliations:
1Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              

Content

show
hide
Free keywords: -
 Abstract: The binding of isolated oxygen atoms to small tantalum clusters is investigated using vibrational spectroscopy. Infrared spectra of TanO⁺ 0;1;2 (n=6–11) are reported in the range of 90–1100 cm -1,comprising both the internal cluster modes and the adatom’s vibrations. The vibrational spectra are compared to the results of DFT calculations for n=6–8, which show that the oxygen atoms bind preferentially as 2-fold bridging adatoms. Addition of one or two O atoms induces only minor distortions of the underlying metal cluster core.

Details

show
hide
Language(s): eng - English
 Dates: 2010-05-26
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 475482
DOI: 10.1021/jp102084n
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Journal of Physical Chemistry A
  Alternative Title : J. Phys. Chem. A
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 114 (36) Sequence Number: - Start / End Page: 9755 - 9761 Identifier: -