English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
  Highly Ordered Mesoporous Carbon as Catalyst for Oxidative Dehydrogenation of Ethylbenzene to Styrene

Su, D. S., Delgado, J. J., Liu, X., Wang, D., Schlögl, R., Wang, L., et al. (2009). Highly Ordered Mesoporous Carbon as Catalyst for Oxidative Dehydrogenation of Ethylbenzene to Styrene. Chemistry - an Asian Journal, 4, 1108-1113. doi:10.1002/asia.200800424.

Item is

Files

show Files
hide Files
:
430430_chemasianj_2009.pdf (Preprint), 655KB
 
File Permalink:
-
Name:
430430_chemasianj_2009.pdf
Description:
-
OA-Status:
Visibility:
Restricted ( Max Planck Society (every institute); )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
736189.pdf (Correspondence), 4MB
 
File Permalink:
-
Name:
736189.pdf
Description:
-
OA-Status:
Visibility:
Private
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Su, Dang Sheng1, Author           
Delgado, Juan Jose1, Author           
Liu, Xi1, Author           
Wang, Di1, Author           
Schlögl, Robert1, Author           
Wang, Lifeng, Author
Zhang, Zhe, Author
Shan, Zhichao, Author
Xiao, Feng-Shou, Author
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

Content

show
hide
Free keywords: dehydrogenation; ethylbeneze; heterogeneous catalysis; mesoporous materials; styrene
 Abstract: We demonstrate that mesoporous carbon without deposition of metal particles is a highly active catalyst. It exhibits both high activity and selectivity in oxidative dehydrogenation of ethylbenzene to styrene, as well as long catalytic stability when compared with activated carbon. Both the as-prepared mesoporous carbon and the active coke formed during the initial stage of the reaction play an important role in the catalytic performance. XPS and IR techniques reveal that the surface oxygen functional groups formed during the reaction are the active sites for the reaction. The ordered mesoporous structure is beneficial for mass transport in catalytic reaction exhibiting long term stability in contrast to activated carbon.

Details

show
hide
Language(s): eng - English
 Dates: 2009-05
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 430430
DOI: 10.1002/asia.200800424
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Chemistry - an Asian Journal
  Alternative Title : Chem. Asian J.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 4 Sequence Number: - Start / End Page: 1108 - 1113 Identifier: -