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  Understanding Palladium Hydrogenation Catalysts: When the Nature of the Reactive Molecule Controls the Nature of the Catalyst Active Phase

Teschner, D., Revay, Z., Borsodi, J., Hävecker, M., Knop-Gericke, A., Schlögl, R., et al. (2008). Understanding Palladium Hydrogenation Catalysts: When the Nature of the Reactive Molecule Controls the Nature of the Catalyst Active Phase. Angewandte Chemie, 120(48), 9414-9418. doi:10.1002/ange.200802134.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0010-FB8B-7 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-96EB-6
Genre: Journal Article

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 Creators:
Teschner, Detre1, Author           
Revay, Zsolt, Author
Borsodi, Janos1, Author           
Hävecker, Michael1, Author           
Knop-Gericke, Axel1, Author           
Schlögl, Robert1, Author           
Milroy, David, Author
Jackson, S. David, Author
Torres, Daniel, Author
Sautet, Philippe, Author
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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Free keywords: Heterogeneous catalysis; Selective hydrogenation; In situ XPS; In situ Prompt Gamma Activation Analysis, DFT Catalytic Hydrogenation
 Abstract: Fundamental differences in the palladium-catalyzed hydrogenation of double and triple C-C bonds arise from marked differences in the composition of the catalyst surface. In situ X-ray photoelectron spectroscopy of the near-surface region of active palladium catalysts uncovers strong links between the chemical nature of the (alkyne/alkene) reactive molecules and the subsurface state of the catalyst.

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Language(s): eng - English
 Dates: 2008-07-102008-11-17
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 394401
DOI: 10.1002/ange.200802134
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Title: Angewandte Chemie
  Alternative Title : Angew. Chem.
Source Genre: Journal
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Pages: - Volume / Issue: 120 (48) Sequence Number: - Start / End Page: 9414 - 9418 Identifier: -