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  Ultrafast changes in the far-infrared conductivity of carbon nanotubes

Frischkorn, C., Kampfrath, T., von Volkmann, K., Perfetti, L., & Wolf, M. (2008). Ultrafast changes in the far-infrared conductivity of carbon nanotubes. In IEEE Digest: 33rd Int. Conf. on Infrared, Millimeter and Terahertz Waves (IRMMW-THz) (pp. 185-185). New York, NY 10017, USA: IEEE.

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 Urheber:
Frischkorn, Christian1, Autor           
Kampfrath, Tobias1, Autor           
von Volkmann, Konrad1, Autor           
Perfetti, Luca, Autor
Wolf, Martin1, Autor           
Affiliations:
1Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              

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 Zusammenfassung: The ultrafast charge-carrier dynamics in single-wall carbon nanotubes (NTs) have been investigated by time-resolved THz spectroscopy. Both the equilibrium and non-equilibrium conductivity data of the NTs in the far-infrared (FIR) spectral range from 1 to 40 THz are dominated by optical transitions across the band gap of tubes with gap energies of ~ 10 meV. A simple model based on an ensemble of two-level systems excellently explains all experimental findings. In particular, the surprisingly weak temperature dependence of the FIR conductivity has been shown to arise from tube-to-tube variation of the chemical potential which is ~ 100 meV in our sample. The results strongly suggest to use the temperature dependence of the FIR conductivity as a very sensitive and contact-free probe of the NT sample purity. Finally, the relaxation of the photo-excited NT sheet on a picosecond time scale mainly reflects the cooling of hot phonons which is about five times faster than in graphite. This points to much stronger lattice anharmonicities in NTs.

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Sprache(n): eng - English
 Datum: 2008-11-05
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Art des Abschluß: -

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Titel: 33rd Int. Conf. on Infrared, Millimeter and Terahertz Waves (IRMMW-THz)
Veranstaltungsort: Pasadena, CA
Start-/Enddatum: 2008-09-15 - 2008-09-19

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Titel: IEEE Digest: 33rd Int. Conf. on Infrared, Millimeter and Terahertz Waves (IRMMW-THz)
Genre der Quelle: Konferenzband
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: New York, NY 10017, USA : IEEE
Seiten: - Band / Heft: - Artikelnummer: - Start- / Endseite: 185 - 185 Identifikator: ISBN: 978-1-4244-2119-0