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  The mechanism of carbonate formation on Pd–Al2O3 catalysts

Föttinger, K., Schlögl, R., & Rupprechter, G. (2008). The mechanism of carbonate formation on Pd–Al2O3 catalysts. Chemical Communications, (3), 320-322. doi:10.1039/b713161e.

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b713161e.pdf (Any fulltext), 292KB
 
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 Creators:
Föttinger, Karin, Author
Schlögl, Robert1, Author           
Rupprechter, Günther, Author
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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Free keywords: Temperature-programmed desorption; Supported metal-catalysts; Co adsorption; Pd nanoparticles; Model catalysts; Palladium; Monoxide; Chemisorption; Hydrogenation; Spectroscopy; CO oxidation on Pd
 Abstract: Vibrational spectroscopic investigations of the adsorption of isotopically labelled and unlabelled CO and CO2 reveal that carbonate formation on Pd–alumina catalysts occurs via an oxygen down reaction of CO with hydroxyl groups on the support, whereas CO dissociation on Pd can be excluded.

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Language(s): eng - English
 Dates: 2008
 Publication Status: Issued
 Pages: -
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 Rev. Type: Peer
 Identifiers: eDoc: 403444
DOI: 10.1039/b713161e
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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : The Society
Pages: - Volume / Issue: (3) Sequence Number: - Start / End Page: 320 - 322 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413