Orientation of nitrous oxide on palladium(110) by STM

Watanabe, Kazuo; Kokalj, Anton; Inokuchi, Yoshiya; Rzeznicka, Izabela; Ohshimo, Keijiro; Nishi, Nobuyuki; Matsushima, Tatsuo

doi:10.1016/j.cplett.2005.03.033

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Orientation of nitrous oxide on palladium(110) by STM

Watanabe, K., Kokalj, A., Inokuchi, Y., Rzeznicka, I., Ohshimo, K., Nishi, N., et al. (2005). Orientation of nitrous oxide on palladium(110) by STM. Chemical Physics Letters, 406(4-6), 474-478. doi:10.1016/j.cplett.2005.03.033.

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Datensatz-Permalink: https://hdl.handle.net/11858/00-001M-0000-0011-08BF-A Versions-Permalink: https://hdl.handle.net/11858/00-001M-0000-0011-08C0-4

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Urheber:
Watanabe, Kazuo¹, Autor
Kokalj, Anton, Autor
Inokuchi, Yoshiya, Autor
Rzeznicka, Izabela, Autor
Ohshimo, Keijiro, Autor
Nishi, Nobuyuki, Autor
Matsushima, Tatsuo, Autor

Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022

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Zusammenfassung: The adsorption structure of N2O on Pd(1 1 0) was analyzed below 14 K by scanning-tunneling microscopy. The N2O monomer was oriented along the [0 0 1] direction in the on-top form. Furthermore, the formation of small aggregates extending along the [1-1 0] direction was observed. The observed images were well-simulated for two types of cluster structures optimized by density-functional theory calculations. The components in the aggregates are proposed to be in a tilted form either on bridge sites or on-top sites.