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  Direct Observation of size Dependent Activation of NO on Gold Clusters

Fielicke, A., Helden, G. v., Meijer, G., Simard, B., & Rayner, D. M. (2005). Direct Observation of size Dependent Activation of NO on Gold Clusters. Physical Chemistry Chemical Physics, 7(23), 3906-3909. doi:10.1039/b511710k.

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b511710k.pdf (Publisher version), 635KB
 
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2005
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 Creators:
Fielicke, André1, Author           
Helden, Gert von1, Author           
Meijer, Gerard1, Author           
Simard, Benoit, Author
Rayner, David M., Author
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1Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              

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 Abstract: Vibrational spectra of NO ligands adsorbed on cationic gold clusters are obtained using IR multiphoton dissociation spectroscopy. We observe a strong oscillation of the NO stretching frequency with increasing cluster size that reveals a clear odd–even dependence in the strength of the NO bond. For the corresponding CO complexes, no oscillation is found. This behaviour can be understood on the basis of the character and occupation of the frontier orbitals of the complexes.

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Language(s): eng - English
 Dates: 2005
 Publication Status: Issued
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 Rev. Type: Peer
 Identifiers: eDoc: 241686
DOI: 10.1039/b511710k
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Title: Physical Chemistry Chemical Physics
  Abbreviation : Phys. Chem. Chem. Phys.
Source Genre: Journal
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Publ. Info: Cambridge, England : Royal Society of Chemistry
Pages: - Volume / Issue: 7 (23) Sequence Number: - Start / End Page: 3906 - 3909 Identifier: ISSN: 1463-9076
CoNE: https://pure.mpg.de/cone/journals/resource/954925272413_1