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  Spectroscopic characterization of organometallic centers on insulator single crystal surfaces: From metal carbonyls to Ziegler–Natta catalysts

Risse, T., & Freund, H.-J. (2005). Spectroscopic characterization of organometallic centers on insulator single crystal surfaces: From metal carbonyls to Ziegler–Natta catalysts. In C. Copéret, & B. Chaudret (Eds.), Surface and Interfacial Organometallic Chemistry and Catalysis (pp. 117-150). Berlin Heidelberg: Springer-Verlag GmbH.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0011-0A34-0 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0011-0A35-E
Genre: Book Chapter

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 Creators:
Risse, Thomas1, Author           
Freund, Hans-Joachim1, Author           
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              

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 Abstract: A detailed knowledge of the microscopic properties is one of the prerequisites for an understanding of heterogeneous catalysts. A strategy which has proven to be valuable in this respect is the use of model systems prepared under well-defined conditions and a subsequent characterization of these systems under both ultrahigh vacuum as well as ambient pressures. In the following review we focus on two systems where organometallic species play an important role. The first class of systems under consideration is metal carbonyls prepared under ultrahigh vacuum conditions. In particular, we will discuss the prospects of these species for use as probes for the environment of the deposited metal atom. In the second part we will discuss experiments on Ziegler–Natta model catalysts. In particular, we will describe how surface science studies of these systems can help to elucidate atomistic properties of surface sites involved in polymerization reactions.

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Language(s): eng - English
 Dates: 2005
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 249406
URI: http://www.springerlink.com/(mrnansro5vhld0454sgj2cjp)/app/home/contribution.asp?referrer=parent&backto=issue,4,8;journal,3,18;linkingpublicationresults,1:110319,1
DOI: 10.1007/b138075
 Degree: -

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Title: Surface and Interfacial Organometallic Chemistry and Catalysis
Source Genre: Book
 Creator(s):
Copéret, Christophe, Editor
Chaudret, Bruno, Editor
Affiliations:
-
Publ. Info: Berlin Heidelberg : Springer-Verlag GmbH
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: 117 - 150 Identifier: ISBN: 3-540-26496-5

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Title: Topics in Organometallic Chemistry
Source Genre: Series
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Pages: - Volume / Issue: 16 Sequence Number: - Start / End Page: - Identifier: -