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  Adsorption of ethylene on stoichiometric RuO2(110)

Paulus, U. A., Wang, Y., Bonzel, H. P., Jacobi, K., & Ertl, G. (2004). Adsorption of ethylene on stoichiometric RuO2(110). Surface Science, 566-568(2), 989-994. doi:10.1016/j.susc.2004.06.041.

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 Creators:
Paulus, Ursula A.1, Author           
Wang, Yuemin1, Author           
Bonzel, Hans P., Author
Jacobi, Karl1, Author           
Ertl, Gerhard1, Author           
Affiliations:
1Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              

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Free keywords: High resolution electron energy loss spectroscopy (HREELS); thermal desorption spectroscopy (TDS); catalysis; adsorption; ruthenium dioxide; ethylene
 Abstract: Ethylene adsorbed on the stoichiometric RuO2(110) surface at 85 K is investigated applying high resolution electron energy loss spectroscopy and thermal desorption spectroscopy in combination with isotope labeling experiments. Under the applied conditions (ultra high vacuum, no continuous reactant supply) ethylene does not react with stoichiometric RuO2(110) and is desorbed molecularly at 320 K. Warming to 260 K leads to a rearrangement of C2H4 from pi- to sigma-bonded.

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Language(s): eng - English
 Dates: 2004-06-15
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 208301
DOI: 10.1016/j.susc.2004.06.041
 Degree: -

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Title: Surface Science
  Alternative Title : Surf. Sci.
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 566-568 (2) Sequence Number: - Start / End Page: 989 - 994 Identifier: -