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Schlagwörter:
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Zusammenfassung:
The model surface Si(111)-(1x1):H is used as a substrate for the adsorption of submonolayer amounts of Li. For n-doped substrates a peak right at the conduction band minimum is found in photoemission spectra. The peak is absent if the experiment is conducted on p-type substrates. Density functional theory calculations for different adsorption sites correlate this peak in the conduction band with Li adsorption in a H3 site of the Si(111)-(1x1):H surface. Experiment and theory show that the binding energy of the spectral feature is independent of the Li coverage. The absence of the structure for p-type substrates suggests a doping dependence of the adsorption site for Li on Si(111)-(1x1):H.
