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  Acetylation and benzoylation of various aromatics on sulfated zirconia

Deutsch, J., Trunschke, A., Müller, D., Quaschning, V., Kemnitz, E., & Lieske, H. (2004). Acetylation and benzoylation of various aromatics on sulfated zirconia. Journal of Molecular Catalysis A: Chemical, 207(1), 51-57. doi:10.1016/S1381-1169(03)00471-0.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0011-0DAA-E Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0011-0DAB-C
Genre: Journal Article

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 Creators:
Deutsch, J., Author
Trunschke, Annette1, Author              
Müller, D., Author
Quaschning, V., Author
Kemnitz, E., Author
Lieske, H., Author
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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Free keywords: Solid acids, Sulfated zirconia, Acylation, Benzophenones, Acetophenones
 Abstract: Sulfated zirconia (SZ) has been found to have a high performance in the benzoylation of anisole. Thus, several aromatics were reacted with benzoic anhydride, benzoyl chloride, and acetic anhydride as acylating agents on SZ, to give the corresponding benzophenones and acetophenones. The rate of the acylation reactions is dependent on the nature of the respective aromatic. The reactivity decreases in the following order: anisole > mesitylene > 3-chloroanisole ∼ m-xylene ∼ 2-chloroanisole > toluene for benzoylations on SZ. The application of SZ as a catalyst for the acetylation of aromatics was only successful in case of anisole.

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Language(s): eng - English
 Dates: 2004-01
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Degree: -

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Title: Journal of Molecular Catalysis A: Chemical
Source Genre: Journal
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Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 207 (1) Sequence Number: - Start / End Page: 51 - 57 Identifier: -