English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
  Infrared Spectroscopy of Neutral C7H7 Isomers: Benzyl and Tropyl

Satink, R. G., Meijer, G., & Helden, G. v. (2003). Infrared Spectroscopy of Neutral C7H7 Isomers: Benzyl and Tropyl. Journal of the American Chemical Society, 125(51), 15714-15715. Retrieved from http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2003/125/i51/abs/ja038329i.html.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0011-0EA1-9 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0011-0EA2-7
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Satink, Rob G., Author
Meijer, Gerard1, Author              
Helden, Gert von1, Author              
Affiliations:
1Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              

Content

show
hide
Free keywords: -
 Abstract: The gas-phase infrared absorption spectra of neutral benzyl and tropyl, isomers of formula C7H7, have been measured in the 400-1800 cm-1 spectral region. In addition, a quantum chemical calculation has been performed to model the infrared spectra. For the benzyl radical, the theory shows satisfactory overlap with the experiment, although vibrations involving the CH2 group might be anharmonic. The tropyl radical, which is subject to the Jahn-Teller effect, seems well modeled for the out-of-plane vibrational modes, but less so for the in-plane vibrational modes.

Details

show
hide
Language(s): eng - English
 Dates: 2003-12-02
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Journal of the American Chemical Society
  Alternative Title : J. Am. Chem. Soc.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 125 (51) Sequence Number: - Start / End Page: 15714 - 15715 Identifier: -