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Schlagwörter:
Thermal desorption spectroscopy; adsorption kinetics; physical adsorption; sticking; oxygen; porous solids; MM3 Force-Field; Hydrocarbons; Adsorption; Mechanics; Kinetics
Zusammenfassung:
The adsorption of oxygen on highly oriented pyrolytic graphite (HOPG) and bundles of single-wall carbon nanotubes (SWNTs) at 28 K is studied using thermal desorption spectroscopy and by a measurement. of sticking probabilities. The low-coverage binding energy of oxygen adsorbed on SWNT bundles, 18.5 kJ/mol, is 55% higher than the low-coverage binding energy on HOPG, 12.0 kJ/mol. Molecular mechanics calculations reveal that such an increase can be attributed to the higher effective coordination of binding sites on SWNT bundles. The character of the oxygen-SWNT interaction should therefore be van der Waals type which suggests that the observed oxygen species is physisorbed and does not facilitate bulk doping of SWNT samples.
