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  High temperature oxidation of Fe-Al and Fe-Cr-Al alloys: The role of Cr as a chemically active element

Airiskallio, E., Nurmi, E., Heinonen, M., Väyrynen, I., Kokko, K., Ropo, M., et al. (2010). High temperature oxidation of Fe-Al and Fe-Cr-Al alloys: The role of Cr as a chemically active element. Corrosion Science, 52(10), 3394-3404. doi:10.1016/j.corsci.2010.06.019.

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Airiskallio , E.1, 2, Author
Nurmi , E.1, 2, 3, Author
Heinonen , M.H.1, 2, Author
Väyrynen , I.J. 1, 2, Author
Kokko , K.1, 2, Author
Ropo, Matti4, 5, Author           
Punkkinen , M.P.J.1, 2, 6, Author
Pitkänen , H.7, Author
Alatalo , M.7, Author
Kollár , J.8, Author
Johansson , B.6, 9, Author
Vitos , L6, 8, 9, Author
Affiliations:
1Univ Turku, Dept Phys & Astron, FI-20014 Turku, Finland , ou_persistent22              
2Turku Univ, Ctr Mat & Surfaces, Turku, Finland , ou_persistent22              
3Grad Sch Mat Res., Turku, Finland , ou_persistent22              
4Abo Akad Univ, Dept Informat Technol, FI-20500 Turku, Finland , ou_persistent22              
5Fritz Haber Institute, Max Planck Society, Berlin, DE, ou_24021              
6Royal Inst Technol, Dept Mat Sci & Engn, SE-10044 Stockholm, Sweden , ou_persistent22              
7Lappeenranta Univ Technol, Dept Math & Phys, FI-53851 Lappeenranta, Finland , ou_persistent22              
8Res Inst Solid State Phys & Opt, H-1525 Budapest, Hungary , ou_persistent22              
9Uppsala Univ, Dept Phys & Mat Sci, SE-75121 Uppsala, Sweden, ou_persistent22              

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 Abstract: Good high-temperature corrosion resistance of Fe-Al alloys in oxidizing environments is due to the alpha-Al2O3 film which is formed on the surface provided temperature is above 900 degrees C and the Al-content of the alloy exceeds the critical value. Ab initio calculations combined with experiments on Fe-13Al, Fe-18Al, Fe-23Al and Fe-10Cr-10Al alloys show that the beneficial effect of Cr on the oxidation resistance is significantly related to bulk effects. The comparison of experimental and calculated results indicates a clear correlation between the Fe-Cr chemical potential difference and the formation of the protective oxide scales. (C) 2010 Elsevier Ltd. All rights reserved

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Language(s): eng - English
 Dates: 2010-10
 Publication Status: Issued
 Pages: 11
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.corsci.2010.06.019
 Degree: -

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Title: Corrosion Science
Source Genre: Journal
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Publ. Info: Amsterdam : Pergamon
Pages: - Volume / Issue: 52 (10) Sequence Number: - Start / End Page: 3394 - 3404 Identifier: ISSN: 0010-938X
CoNE: https://pure.mpg.de/cone/journals/resource/954925393343