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  Carbon-Catalyzed Oxidative Dehydrogenation of n-Butane: Selective Site Formation during sp3-to-sp2 Lattice Rearrangement

Liu, X., Frank, B., Zhang, W., Cotter, T. P., Schlögl, R., & Su, D. S. (2011). Carbon-Catalyzed Oxidative Dehydrogenation of n-Butane: Selective Site Formation during sp3-to-sp2 Lattice Rearrangement. Angewandte Chemie Internationale Edition, 50(14), 3318-3322. doi:10.1002/anie.201006717.

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 Creators:
Liu, Xi1, Author              
Frank, Benjamin1, Author              
Zhang, Wei1, Author              
Cotter, Thomas Patric1, Author              
Schlögl, Robert1, Author              
Su, Dang Sheng1, 2, Author              
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
2Shenyang National Laboratory for Materials Science Institute of Metal Research, Chinese Academy of Science, 72 Wenhua Road, Shenyang 110016 (China), ou_persistent22              

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Free keywords: catalysis; nanodiamonds; nano‒onions; phase transitions; surface activation
 Abstract: While catalyzing the oxidative dehydrogenation of n-butane, ultradispersed nanodiamonds (UDD) are transformed into onionlike carbon (OLC, see picture). This surface-activated bulk transformation from sp3- to sp2-hybridized carbon atoms is concomitant with an enhanced product selectivity to the desired butenes. In addition, the synthesis of OLC is achieved at temperatures 600 K lower than reported so far.

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Language(s): eng - English
 Dates: 2011-03-012011-03-28
 Publication Status: Published in print
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 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201006717
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Title: Angewandte Chemie Internationale Edition
Source Genre: Journal
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Publ. Info: Weinheim : Verlag Chemie
Pages: - Volume / Issue: 50 (14) Sequence Number: - Start / End Page: 3318 - 3322 Identifier: ISSN: 0044-8249
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058_1