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Surface Sensitive Study To Determine the Reactivity of Soot with the Focus on the European Emission Standards IV and VI

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Schuster,  Manfred Erwin
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Hävecker,  Michael
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Arrigo,  Rosa
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Blume,  Raoul
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22148

Su,  Dang Sheng
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Schuster, M. E., Hävecker, M., Arrigo, R., Blume, R., Knauer, M., Ivleva, N. P., et al. (2011). Surface Sensitive Study To Determine the Reactivity of Soot with the Focus on the European Emission Standards IV and VI. The Journal of Physical Chemistry A, 115(12), 2568-2580. doi:10.1021/jp1088417.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-0C00-5
Abstract
Diesel soot (Euro IV and Euro VI) was investigated with spectroscopic methods such as near-edge X-ray absorption fine structure (NEXAFS) spectroscopy and X-ray photoemission spectroscopy (XPS). C and O K-edge NEXAFS show that structural disorder on the surface is accompanied by a higher amount of oxygen functional groups. O K-edge NEXAFS and O1s XPS results are discussed with the aim to elucidate the nature of the oxygen surface species. The analysis of the data presented here allows the postulation of a hypothetical structure for soot samples emitted by diesel engines.