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Knowledge-based development of a nitrate-free synthesis route for Cu/ZnO methanol synthesis catalysts via formate precursors

MPS-Authors
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Behrens,  Malte
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Kißner,  Stefan
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Girgsdies,  Frank
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Kasatkin,  Igor
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21624

Hermerschmidt,  Felix
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Mette,  Katharina
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Behrens, M., Kißner, S., Girgsdies, F., Kasatkin, I., Hermerschmidt, F., Mette, K., et al. (2011). Knowledge-based development of a nitrate-free synthesis route for Cu/ZnO methanol synthesis catalysts via formate precursors. Chemical Communications, 47(6), 1701-1703. doi:10.1039/C0CC04933F.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0012-0DBC-C
Abstract
High-performance Cu/ZnO/(Al2O3) methanol synthesis catalysts are conventionally prepared by co-precipitation from nitrate solutions and subsequent thermal treatment. A new synthesis route is presented, which is based on similar preparation steps and leads to active catalysts, but avoids nitrate contaminated waste water.