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Boundary slip as a result of a prewetting transition

MPG-Autoren
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Andrienko,  D.
MPI for Polymer Research, Max Planck Society;

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Dünweg,  Burkhard
MPI for Polymer Research, Max Planck Society;

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Vinogradova,  Olga I.
MPI for Polymer Research, Max Planck Society;

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Zitation

Andrienko, D., Dünweg, B., & Vinogradova, O. I. (2003). Boundary slip as a result of a prewetting transition. Journal of Chemical Physics, 119(24), 13106-13112.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-000F-63D9-8
Zusammenfassung
Some fluids exhibit anomalously low friction when flowing against a certain solid wall. To recover the viscosity of a bulk fluid, slip at the wall is usually postulated. On a macroscopic level, a large slip length can be explained as a formation of a film of gas or phase-separated "lubricant" with lower viscosity between the fluid and the solid wall. Here we justify such an assumption in terms of a prewetting transition. In our model the thin-thick film transition together with the viscosity contrast gives rise to a large boundary slip. The calculated value of the slip length has a jump at the prewetting transition temperature which depends on the strength of the fluid-surface interaction (contact angle). Furthermore, the temperature dependence of the slip length is nonmonotonous. ©2003 American Institute of Physics.