English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Dipolar recoupling in NOESY-Type H-1-H-1 NMR experiments under HRMAS conditions

MPS-Authors
/persons/resource/persons48862

Thieme,  K.
MPI for Polymer Research, Max Planck Society;

/persons/resource/persons48786

Spiess,  Hans Wolfgang
MPI for Polymer Research, Max Planck Society;

/persons/resource/persons48720

Schnell,  Ingo
MPI for Polymer Research, Max Planck Society;

External Ressource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Thieme, K., Zech, G., Kunz, H., Spiess, H. W., & Schnell, I. (2002). Dipolar recoupling in NOESY-Type H-1-H-1 NMR experiments under HRMAS conditions. Organic Letters, 4(9), 1559-1562.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-6609-6
Abstract
The concept of dipolar recoupling is introduced to H-1-H-1 NOESY experiments performed under HRMAS conditions. Dipole- dipole couplings are selectively recoupled during the mixing period, while MAS ensures high resolution in the spectral dimensions. Incoherent dipolar exchange is replaced by amplified coherent processes, such that time scales for polarization transfer are shortened, and dipolar double-quantum techniques become applicable. In this way, dipole-dipole couplings, as well as J-couplings, can be individually measured.