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Synthesis and structural studies of some selenoureas and their metal complexes

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Rust,  Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Molter, A., Rust, J., Lehmann, C. W., & Mohr, F. (2011). Synthesis and structural studies of some selenoureas and their metal complexes. Arkivoc, (6), 10-17. doi:10.3998/ark.5550190.0012.602.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8C5F-0
Abstract
The selenoureas PhC(O)NHC(Se)NPhMe, 4-MeC6H4C(O)NHC(Se)NPhMe and 4-MeC6H4C(O)-NHC(Se)NEt2 were prepared and characterized by spectroscopic methods and single crystal X-ray diffraction. 4-MeC6h4C(O)NHC(Se)NEt2 was reacted with some Pt(II), Pd(II) and Ru(II) precursers to give heteroleptic, cationic metal complexes which were characterized by NMR spectroscopy, electron mass spectrometry and, in the case of the Pd(II) complex [Pd{4-MeC6H4C(O)NC(Se)NEt2}{tBu2bipy)]PF6 by X-ray diffraction.