Catalytic Asymmetric Reductive Amination of α-Branched Ketones

Wakchaure, Vijay N.; Zhou, Jian; Hoffmann, Sebastian; List, Benjamin

doi:10.1002/anie.201001715

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Catalytic Asymmetric Reductive Amination of α-Branched Ketones

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Wakchaure, Vijay N.
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Zhou, Jian
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Hoffmann, Sebastian
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Wakchaure, V. N., Zhou, J., Hoffmann, S., & List, B. (2010). Catalytic Asymmetric Reductive Amination of α-Branched Ketones. Angewandte Chemie International Edition, 49(27), 4612-4614. doi:10.1002/anie.201001715.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8D8D-6

Abstract

Branching out: An organocatalytic reductive amination of α‐branched ketones using dynamic kinetic resolution is reported. The cis‐2‐substituted cyclohexyl amines were obtained in high diastereoselectivity and enantioselectivity from the corresponding ketones.