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Towards a Practical Brønsted Acid Catalyzed and Hantzsch Ester Mediated Asymmetric Reductive Amination of Ketones with Benzylamine

MPS-Authors
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Wakchaure,  Vijay N.
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Nicoletti,  Marcello
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ratjen,  Lars
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Wakchaure, V. N., Nicoletti, M., Ratjen, L., & List, B. (2010). Towards a Practical Brønsted Acid Catalyzed and Hantzsch Ester Mediated Asymmetric Reductive Amination of Ketones with Benzylamine. Synlett, (18), 2708-2710. doi:10.1055/s-0030-1259003.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8D91-9
Abstract
We report the use of benzylamine as the amine component in Hantzsch ester mediated and chiral Brønsted acid catalyzed enantioselective reductive aminations of ketones. The method is noteworthy because the benzyl group is easily removable, and amine product purification is achieved through Hantzsch ester oxidation product removal via basic hydrolysis.