English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Catalytic Asymmetric Epoxidation of α-Branched Enals

MPS-Authors
/persons/resource/persons58757

Lifchits,  Olga
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58922

Reisinger,  Corinna Marie
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58764

List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Ressource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Lifchits, O., Reisinger, C. M., & List, B. (2010). Catalytic Asymmetric Epoxidation of α-Branched Enals. Journal of the American Chemical Society, 132(30), 10227-10229. doi:10.1021/ja1037935.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-8DB5-A
Abstract
An asymmetric catalytic epoxidation of α-branched, α,β-unsaturated aldehydes is presented. A highly synergistic combination of a primary cinchona-based amine and a chiral phosphoric acid was found to promote the reaction with excellent enantiocontrol for α-monosubstituted and α,β-disubstituted enals.